Part 4: Ship|shore (tanker/terminal) interface
Contents:-
Part 1: General Information
Chapter 1 – Basic: properties of petroleum
Chapter 2- Hazards of petroleum
Chapter 3- Static electricity
Chapter 4 – General hazards for ship and terminal
Chapter 5- Fire fighting
Chapter 6- Security
Part 2: Tanker Information
Chapter 7 – Shipboard system
Chapter 8- Ship’s equipment
Chapter 9- Management of safety & emergencies
Chapter 10- Enclosed space
Chapter 11- Shipboard operations
Chapter 12- Carriage & stowage of hazardous material
Chapter 13- Human element consideration
Chapter 14- Special ship type
Part 3: Terminal Information
Chapter 15- Terminal management and organisation
Chapter 16- Terminal operations
Chapter 17- Terminal systems and equipment
Chapter 18- Cargo transfer equipment
Chapter 19- Safety and fire protection
Chapter 20- Emergency preparedness
Chapter 21- Emegency evacuation
Part 4: Ship/Shore Interface
Chapter 22- Communication
Chapter 23- Mooring
Chapter 24- Precautions on ship & terminal during cargo operation.
Chapter 25- Bunkering operation
Chapter 26- Safety management

A flammability diagram explains to us how a gas or a mixture of two gases will behave and catch fire when diluted with another gas or air.
The flammability diagram is the key element for planning a safe operation on board a ship.
For example, let’s say we get lower flammability limit 1% (Point C) & upper flammability limit 10% (Point D) from MSDS of a crude oil.
For understanding, let’s take point F as a condition in our tank. At point F, HC gas is approximately 11% & oxygen is approximately 2%.
Now, at this point, if we do dilution with air, it will follow the path AF, i.e. HC gas component keeps on decreasing & the oxygen content keeps on increasing gradually (because oxygen is present in the air).
At a particular point, this line will come in contact with the flammability mixture curve & there will be a high chance of explosion.
So, we will use inert gas to lower the HC gas component & little bit of oxygen content till point H.
After dilution with I.G., we can dilute with air; it will follow the path AH, and it will be much safer as it is far away from the flammability curve & there will be very less chances of explosion.
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